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a photograph of the MTEC unit which mounts directly in the
sample compartment of the FTIR's optical bench.
Fig. 3. MTEC Model 200 photoacoustic detector
mounted on a
Nicolet sample compartment baseplate.

The spectral range of a photoacoustic detector depends
only on the transparency of the sample chamber window. With suitable
windows a detector can operate from the UV to the far-infrared.
The most common window material is KBr (UV through mid-infrared),
but quartz (UV through near-infrared), CsI (UV - 200
cm-1), ZnSe
(near-infrared - 560 cm-1), and
polyethylene (far-infrared) are
also frequently used.
The maximum MTEC sample holder dimensions are 10.7
mm in diameter by 9.0 mm deep. Most analyses require a much smaller
sample volume. Sample holder inserts are provided to displace
unused gas volume and boost the signal level which is proportional
to the reciprocal of the gas volume.
Only the central region of the MTEC sample chamber
is irradiated by the infrared beam because the photoacoustic
detector's mirror causes a factor of two diameter reduction in
the FTIR beam focal-spot diameter, this size is reduced to a
5 mm diameter inside the detector sample holder at the focal
plane position which is approximately 1.0 mm to 1.5 mm below
the detector window. Consequently, the sample volume that is
actually analyzed is approximated by the focal area times the
sampling depth, L, which |